VVT-i

VVT-i, or Variable Valve Timing with intelligence, is an automobile variable valve timing technology developed by Toyota. The Toyota VVT-i system replaces the Toyota VVT offered starting in 1991 on the 4A-GE 20-Valve engine. The VVT system is a 2-stage hydraulically controlled cam phasing system.

VVT-i, introduced in 1996, varies the timing of the intake valves by adjusting the relationship between the camshaft drive (belt, scissor-gear or chain) and intake camshaft. Engine oil pressure is applied to an actuator to adjust the camshaft position. In 1998, 'Dual' VVT-i (adjusts both intake and exhaust camshafts) was first introduced in the RS200 Altezza's 3S-GE engine. Dual VVT-i is also found in Toyota's new generation V6 engine, the 3.5L 2GR-FE V6. This engine can be found in the Avalon, RAV4, and Camry in the US, the Aurion in Australia, and various models in Japan, including the Estima. Other Dual VVT-i engines will be seen in upcoming Toyota models, including a new 4 cylinder Dual VVT-i engine for the new generation 2007/2008 Corolla. Another notable implementation of the Dual VVT-i is the 2GR-FSE D-4S engine of the Lexus GS450h. By adjusting the valve timing, engine start and stop occur virtually unnoticable at minimum compression, and fast heating of the catalytic converter to its light-off temperature is possible, thereby reducing HC emissions considerably.

In 1998, Toyota started offering a new technology, VVTL-i, which can alter valve lift (and duration) as well as valve timing. In the case of the 16 valve 2ZZ-GE, the engine has 2 camshafts, one operating intake valves and one operating exhaust valves. Each camshaft has two lobes per cylinder, one low rpm lobe and one high rpm, high lift, long duration lobe. Each cylinder has two intake valves and two exhaust valves. Each set of two valves are controlled by one rocker arm, which is operated by the camshaft. Each rocker arm has a slipper follower mounted to the rocker arm with a spring, allowing the slipper follower to move up and down with the high lobe with out affecting the rocker arm. When the engine is operating below 6000 rpm, the low lobe is operating the rocker arm and thus the valves. When the engine is operating above 6000 rpm, the ECU activates an oil pressure switch which pushes a sliding pin under the slipper follower on each rocker arm. This in effect, switches to the high lobe causing high lift and longer duration.

Toyota has now ceased production of its VVTL-i engines for most markets, because the engine does not meet Euro IV specifications for emissions. As a result, some Toyota models have been discontinued, including the Corolla T-Sport (Europe), Corolla Sportivo (Australia), Celica, Corolla XRS, Toyota Matrix XRS, and the Pontiac Vibe GT, all of which had the 2ZZ-GE engine fitted.

Two-way catalytic converters

A two-way catalytic converter has two simultaneous tasks:

1. Oxidation of carbon monoxide to carbon dioxide: 2CO + O₂ → 2CO₂
2. Oxidation of unburnt hydrocarbons (unburnt and partially-burnt fuel) to carbon dioxide and water: 2C_xH_y + (2x+y/2)O₂ → 2xCO₂ + yH₂O

This type of catalytic converter is widely used on diesel engines to reduce hydrocarbon and carbon monoxide emissions. They were also used on spark ignition (gasoline) engines in USA market automobiles up until 1981, when they were replaced by three-way converters due to regulatory changes requiring reductions on NO_x emissions. Reduction of the NO_x emissions requires an additional step. Platinum catalysis can be used.

Instead of catalysis, for diesel engines a true reactant, ammonia pyrolyzed in situ from urea, can be used to reduce the NO_x into nitrogen, see AdBlue.

The regulations regarding hydrocarbons vary according to the engine regulated, as well as the jurisdiction. In some cases, "non-methane hydrocarbons" are regulated, while in other cases, "total hydrocarbons" are regulated. Technology for one application (to meet a non-methane hydrocarbon standard) may not be suitable for use in an application that has to meet a total hydrocarbon standard. Methane is not toxic, but is more difficult to break down in a catalytic converter, so in effect a "non-methane hydrocarbon" standard can be considered to be looser. Since methane is a greenhouse gas, interest is rising in how to eliminate emissions of it.

catalytic converter

A catalytic converter automobiles in the (colloquially, 'cat' or 'catcon') is a device used to reduce the toxicity of emissions from an internal combustion engine. First widely introduced on series-productionUS market for the 1975 model year to comply with tightening EPA regulations on auto exhaust, catalytic converters are still most commonly used in motor vehicle exhaust systems. Catalytic converters are also used on generator sets, forklifts, mining equipment, trucks, buses, trains, and other engine-equipped machines. A catalytic converter provides an environment for a chemical reaction wherein toxic combustion byproducts are converted to less-toxic gases. The catalytic converter was invented at Trinity College (Connecticut).

Three-way catalytic converters

A three-way catalytic converter has three simultaneous tasks:

1. Reduction of nitrogen oxides to nitrogen and oxygen: 2NO_x → xO₂ + N₂
2. Oxidation of carbon monoxide to carbon dioxide: 2CO + O₂ → 2CO₂
3. Oxidation of unburnt hydrocarbons (HC) to carbon dioxide and water: 2C_xH_y + (2x+y/2)O₂ → 2xCO₂ + yH₂O

These three reactions occur most efficiently when the catalytic converter receives exhaust from an engine running slightly above the stoichiometric point. This is between 14.8 and 14.9 parts air to 1 part fuel, by weight, for gasoline (the ratio for LPG, natural gas and ethanol fuels is slightly different, requiring modified fuel system settings when using those fuels). When there is more oxygen than required, then the system is said to be running lean, and the system is in oxidizing condition. In that case, the converter's two oxidizing reactions (oxidation of CO and hydrocarbons) are favoured, at the expense of the reducing reaction. When there is excessive fuel, then the engine is running rich. The reduction of NO_x is favoured, at the expense of CO and HC oxidation. If an engine could be operated with infinitesimally small oscillationsn about the stoichiometric point for the fuel used, it is theoretically possible to reach 100% conversion efficiencies.

Since 1981, three-way catalytic converters have been at the heart of vehicle emission control systems in North American roadgoing vehicles, and have been used on "large spark ignition" (LSI) engines since 2001 in California, and from 2004 in the other 49 states LSI engines are used in forklifts, aerial boom lifts, ice resurfacing machines and construction equipment. The converters used in those types of machines are three-way types, and are designed to reduce combined NO_x+HC emissions from 12 gram/BHP-hour to 3 gram/BHP-hour or less, as mandated by the United States Environmental Protection Agency's (EPA) 2004 regulations A further drop to 2 gram/BHP-hour of NO_x+HC emissions is mandated in 2007note: NO_x is the industry standard short form for nitric oxide (NO) and nitrogen dioxide (NO₂) both of which are smog precursors. HC is the industry short form for hydrocarbons). The EPA intends to introduce emissions rules for stationary spark ignition engines, to take effect in January 2008.